Europium

For color TV tubes.

History

(Europe) In 1890 Boisbaudran obtained basic fractions from samarium-gadolinium concentrates which had spark spectral lines not accounted for by samarium or gadolinium. These lines subsequently have been shown to belong to europium. The discovery of europium is generally credited to Demarcay, who separated the rare earth in reasonably pure form in 1901. The pure metal was not isolated until recent years.

Production

Europium is now prepared by mixing Eu2O3 with a 10%-excess of lanthanum metal and heating the mixture in a tantalum crucible under high vacuum. The element is collected as a silvery-white metallic deposit on the walls of the crucible.

Properties

As with other rare-earth metals, except for lanthanum, europium ignites in air at about 150 to 180oC. Europium is about as hard as lead and is quite ductile. It is the most reactive of the rare-earth metals, quickly oxidizing in air. It resembles calcium in its reaction with water. Bastnasite and monazite are the principal ores containing europium.

Sources

Europium has been identified spectroscopically in the sun and certain stars. Seventeen isotopes are now recognized. Europium isotopes are good neutron absorbers and are being studied for use in nuclear control applications.

Uses

Europium oxide is now widely used as a phospor activator and europium-activated yttrium vanadate is in commercial use as the red phosphor in color TV tubes. Europium-doped plastic has been used as a laser material. With the development of ion-exchange techniques and special processes, the cost of the metal has been greatly reduced in recent years.

Cost

Europium is one of the rarest and most costly of the rare-earth metals. It is priced about about $7500/kg.

Sources: CRC Handbook of Chemistry and Physics and the American Chemical Society.